10 Former Celebrity Couples You Probably Never Knew Dated

Wait, Kim Kardashian dated him? Rihanna dated who?

Jessica Biel and Chris Evans (Photo by Jean-Paul Aussenard/WireImage for Bragman Nyman Cafarelli)
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Jessica Biel & Chris Evans

Long before meeting her now-husband Justin Timberlake, Biel was in a serious, five-year relationship with Captain America. In fact, it was so serious that the two considered marriage. “We always talk about it,” the 7th Heaven actor told Cosmo in 2005. “We both want to be married, and we both want to have children. But we’re not engaged, so the rumors are false … so far.”

Lourdes Leon & Timothée Chalamet

Madonna’s daughter shook the Chalamet hive when she revealed that she used to date the Call Me By You Name actor. “I respect him a lot,” Leon told Vanity Fair in an April 2021 interview. “We were a little item. My first boyfriend.”